“…Physical vapor deposition could avoid the complex set of interrelated growth parameters governing CVD processes. While commonly associated with polycrystalline thin films, for example, in metallurgical coatings or transparent conducting oxides, magnetron sputtering has been used to grow epitaxial metals,22,23 compounds,24 and semiconductor heterostructures,25 including high electron mobility modulation-doped quantum wells 26. Here we demonstrate the growth of high quality few-layer BN films with controlled thickness using reactive magnetron sputtering of B in N 2 /Ar, a scalable, industry-compatible process that uses only benign, nontoxic reagents.The glow discharge of the magnetron sputtering process plays two important roles in the growth of BN films (Figure1a):27,28 (i) evaporation of B by collision cascades due to the impact of energetic Ar + ions on a solid B target; and (ii) generation of nitrogen radicals via dissociation of gas phase N 2 by free electrons and ions in the plasma.…”