In this paper the interaction potentials of relativistic electrons with the charged (2m+1, 2n+1, 2p+1) and (2m+1, 2n, 2p) planes (m, n, p=0,1,ṡ, and Miller indices are mutually prime numbers) in the crystals with a zinc blende structure are calculated using Moliere approximation. It is shown that at the change of the type of used crystal plane (from the main (100) to the high-index charged planes), the structures of potential wells are transformed from non-unimodal to unimodal ones. In this case for the crystals constructed from ions with close nucleus charges, there arise so-called positron-like potential wells for the channeled electrons, i.e. with minima in the interplanar space. The influence of temperature factor on interaction potentials structures is also investigated. For the electrons with Lorentz-factors γ = 25, 50, 75 in the main (100) and (111) planes the transverse energy levels and corresponding wave functions in single planar approximation are found numerically. By means of these data the spectra of channeling radiation (CR) in dipole approximation are calculated for the electrons beams with a Lorentz-factor γ = 50 and an angular dispersion θ 0 ≈ 0,5 mrad, arising in the main charged (100) and (111) planes in ZnS, ZnSe and ZnTe crystals. It is shown that the CR generated at electron channeling along the (111) planes is more intense. It is shown also that spectra of CR arising in (111) planes of silicon and AlP crystals at using of channeled electron beam with γ = 25 and an angular dispersion θ 0 ≈ 0,5 mrad, due to similarity of structures of potential wells are identical. The spectra of CR at γ = 25, 50, 75 are calculated for a number of crystals with a zinc blende structure, namely AlP, AlAs, AlSb, GaP, GaAs, InP, InAs, InSb.