In this study, we develop the generalized Dirac like four-momentum equation for rotating spin-half particles in four-dimensional quaternionic algebra. The generalized quaternionic Dirac equation consists the rotational energy and angular momentum of particle and anti-particle. Accordingly, we also discuss the four vector form of quaternionic relativistic mass, moment of inertia and rotational energy-momentum in Euclidean space-time. The quaternionic four angular momentum (i.e. the rotational analogy of four linear momentum) predicts the dual energy (rest mass energy and pure rotational energy) and dual momentum (linear like momentum and pure rotational momentum). Further, the solutions of quaternionic rotational Dirac energy-momentum are obtained by using one, two and fourcomponent of quaternionic spinor. We also demonstrate the solutions of quaternionic plane wave equation which gives the rotational frequency and wave propagation vector of Dirac particles and anti-particles in terms of quaternionic form. PACS: 03.65.−w, 03.65.Fd, 02.10.Ud relativistic velocity. To combine the special theory of relativity with quantum mechanics, there has been developed the relativistic quantum mechanics. In the same way, Klein-Gordon and Dirac independently investigated the relativistic wave equations by combining special relativity with quantum mechanics. These relativistic wave equations describe the various phenomenons that occur in high energy physics and are invariant under Lorentz transformations. Dirac [1] discussed a relativistic quantum wave equation by using Hamiltonian operator to overcome the difficulties arising in Klein-Gordon equation. As we know that the conservation of energy and angular momentum are one of the mandatory conservation laws to check the validity of Dirac particles. Keeping in mind the conservation laws of energy and angular momentum of a rotating particle, in this paper, we proposed a quaternionic Dirac equation that consists not only the energy representation but also shows the angular momentum representation of spin-1/2 particles. The quaternion number [2] is basically an extension of complex numbers. Although, there are four types of norm-division algebras, i.e. real, complex, quaternion and octonion algebra. The division algebra is defined as an algebra in which all non-zero elements have their inverse under multiplication [3]. Nowadays, the quaternionic algebra is a popular algebra to study the various theories in modern theoretical physics. The quaternionic algebra is associative and commutative under addition but not commutative under multiplication. Thus, this algebra form a group under multiplication but not an Abelian group, is also called the division ring. Many researchers have attempted the formulation of usual Dirac equation for free particles in terms of quaternionic algebra. Firstly, Rotelli [4] developed the Dirac equation in quaternionic four fields. The another version of quaternionic Dirac equation has been studied by Rawat et. al [5] with the description of quaternionic spinor...