Owing to the difference in K-theory, an example by Dugger and Shipley implies that the equivalence of stable categories of Gorenstein projective modules should not be a Quillen equivalence. We give a sufficient and necessary condition such that the Frobenius pair of faithful functors between two abelian categories is a Quillen equivalence, which is equivalent to that the Frobenius functors induce mutually inverse equivalences between stable categories of Gorenstein projective objects.We show that the category of Gorenstein projective objects is a Waldenhausen category, then Gorenstein K-groups are introduced and characterized. As applications, we show that stable equivalences of Morita type preserve Gorenstein K-groups, CM-finite and CM-free. Two specific examples are presented to illustrate our results, where Gorenstein K 0 and K 1 -groups are calculated.