Quinoline‐Flanked Diketopyrrolopyrrole Copolymers Breaking through Electron Mobility over 6 cm2 V−1 s−1 in Flexible Thin Film Devices

Ni, Zhiyu; Dong, Huanli; Wang, Hanlin; Ding, Shang; Zou, Ye; Zhao, Qiang; Zhen, Yonggang; Liu, Feng; Jiang, Lang; Hu, Wenping

doi:10.1002/adma.201704843

Cited by 110 publications

(83 citation statements)

References 24 publications

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“…Another approach was reported by Ni et al, who copolymerized a quinoline‐flanked DPP unit with a perfluorinated thiophene unit ( P47 ) . This quinoline‐flanked DPP unit lowered the LUMO level to −3.84 eV.…”

Section: Molecular Design Strategies For High‐performance D–a‐conjugamentioning

confidence: 99%

Donor–Acceptor‐Conjugated Polymer for High‐Performance Organic Field‐Effect Transistors: A Progress Report

Kim

Ryu

Park

et al. 2019

Adv Funct Materials

331

318

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Polymeric semiconductors have demonstrated great potential in the mass production of low-cost, lightweight, flexible, and stretchable electronic devices, making them very attractive for commercial applications. Over the past three decades, remarkable progress has been made in donor-acceptor (D-A) polymer-based field-effect transistors, with their charge-carrier mobility exceeding 10 cm 2 V −1 s −1 . Numerous molecular designs of D-A polymers have emerged and evolved along with progress in understanding the charge transport physics behind their high mobility. In this review, the current understanding of charge transport in polymeric semiconductors is covered along with significant features observed in high-mobility D-A polymers, with a particular focus on polymeric microstructures. Subsequently, emerging molecular designs with further prospective improvements in charge-carrier mobility are described. Moreover, the current issues and outlook for future generations of polymeric semiconductors are discussed.

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Section: Molecular Design Strategies For High‐performance D–a‐conjugamentioning

confidence: 99%

Donor–Acceptor‐Conjugated Polymer for High‐Performance Organic Field‐Effect Transistors: A Progress Report

Kim

Ryu

Park

et al. 2019

Adv Funct Materials

331

318

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“…Moreover, most are intrinsically unipolar materials. Recently, high‐performance balanced ambipolar organic semiconductors, in particular, those composed of conjugated polymers, have been developed; however, most show weak or even no emission. The development of high‐performance emissive organic semiconductors is crucial for high OLETs and electrically pumped organic lasers.…”

Section: Conclusion and Outlooksmentioning

confidence: 99%

Organic Semiconductor Single Crystals for Electronics and Photonics

2018

Self Cite

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Organic semiconducting single crystals (OSSCs) are ideal candidates for the construction of high-performance optoelectronic devices/circuits and a great platform for fundamental research due to their long-range order, absence of grain boundaries, and extremely low defect density. Impressive improvements have recently been made in organic optoelectronics: the charge-carrier mobility is now over 10 cm V s and the fluorescence efficiency reaches 90% for many OSSCs. Moreover, high mobility and strong emission can be integrated into a single OSSC, for example, showing a mobility of up to 34 cm V s and a photoluminescence yield of 41.2%. These achievements are attributed to the rational design and synthesis of organic semiconductors as well as improvements in preparation technology for crystals, which accelerate the application of OSSCs in devices and circuits, such as organic field-effect transistors, organic photodetectors, organic photovoltaics, organic light-emitting diodes, organic light-emitting transistors, and even electrically pumped organic lasers. In this context, an overview of these fantastic advancements in terms of the fundamental insights into developing high-performance organic semiconductors, efficient strategies for yielding desirable high-quality OSSCs, and their applications in optoelectronic devices and circuits is presented. Finally, an overview of the development of OSSCs along with current challenges and future research directions is provided.

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“…All reagents were purchased from Sigma Aldrich (St. Louis, MO, USA) and used without further purification. 3-Bromothieno[3,2- b ]thiophene, 2,5-bis(trimethylstannyl)thiophene (M1), and 2,5-bis(trimethylstannyl)thieno[3,2- b ]thiophene (M2) were synthesized according to previously reported methods [ 27 , 28 , 29 ].…”

Section: Methodsmentioning

confidence: 99%

Novel Conjugated Polymers Containing 3-(2-Octyldodecyl)thieno[3,2-b]thiophene as a π-Bridge for Organic Photovoltaic Applications

Park

et al. 2020

Polymers

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3-(2-Octyldodecyl)thieno[3,2-b]thiophen was successfully synthesized as a new π-bridge with a long branched side alkyl chain. Two donor-π-bridge-acceptor type copolymers were designed and synthesized by combining this π-bridge structure, a fluorinated benzothiadiazole acceptor unit, and a thiophene or thienothiophene donor unit, (PT-ODTTBT or PTT-ODTTBT respectively) through Stille polymerization. Inverted OPV devices with a structure of ITO/ZnO/polymer:PC71BM/MoO3/Ag were fabricated by spin-coating in ambient atmosphere or N2 within a glovebox to evaluate the photovoltaic performance of the synthesized polymers (effective active area: 0.09 cm2). The PTT-ODTTBT:PC71BM-based structure exhibited the highest organic photovoltaic (OPV) device performance, with a maximum power conversion efficiency (PCE) of 7.05 (6.88 ± 0.12)%, a high short-circuit current (Jsc) of 13.96 mA/cm2, and a fill factor (FF) of 66.94 (66.47 ± 0.63)%; whereas the PT-ODTTBT:PC71BM-based device achieved overall lower device performance. According to GIWAXS analysis, both neat and blend films of PTT-ODTTBT exhibited well-organized lamellar stacking, leading to a higher charge carrier mobility than that of PT-ODTTBT. Compared to PT-ODTTBT containing a thiophene donor unit, PTT-ODTTBT containing a thienothiophene donor unit exhibited higher crystallinity, preferential face-on orientation, and a bicontinuous interpenetrating network in the film, which are responsible for the improved OPV performance in terms of high Jsc, FF, and PCE.

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Quinoline‐Flanked Diketopyrrolopyrrole Copolymers Breaking through Electron Mobility over 6 cm² V⁻¹ s⁻¹ in Flexible Thin Film Devices

Cited by 110 publications

References 24 publications

Donor–Acceptor‐Conjugated Polymer for High‐Performance Organic Field‐Effect Transistors: A Progress Report

Donor–Acceptor‐Conjugated Polymer for High‐Performance Organic Field‐Effect Transistors: A Progress Report

Organic Semiconductor Single Crystals for Electronics and Photonics

Novel Conjugated Polymers Containing 3-(2-Octyldodecyl)thieno[3,2-b]thiophene as a π-Bridge for Organic Photovoltaic Applications

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