Heat conductivity of the spin-Peierls compounds TiOCl and TiOBr Hlubek, N.; Sing, M.; Glawion, S.; Claessen, R.; van Smaalen, S.; van Loosdrecht, P. H. M.; Buechner, B.; Hess, C.; Büchner, B. We report experimental results on the heat conductivity of the S =1/ 2 spin chain compounds TiOBr and TiOCl for temperatures 5 K Ͻ T Ͻ 300 K and magnetic fields up to 14 T. Surprisingly, we find no evidence of a significant magnetic contribution to , which is in stark contrast to recent results on S =1/ 2 spin chain cuprates. Despite this unexpected result, the thus predominantly phononic heat conductivity of these spinPeierls compounds exhibits a very unusual behavior. In particular, we observe strong anomalies at the phase transitions T c1 and T c2 . Moreover, we find an overall but anisotropic suppression of in the intermediate phase which extends even to temperatures higher than T c2 . An external magnetic field causes a slight downshift of the transition at T c1 and enhances the suppression of up to T c2 . We interpret our findings in terms of strong spin-phonon coupling and phonon scattering arising from spin-driven lattice distortions.