In this paper we study properties of series with respect to orthogonal systems {r i (t)r j (t)} i =j and {r i (s)r j (t)} ∞ i,j=1 in symmetric spaces on interval and square, respectively. Necessary and sufficient conditions for the equivalence of these systems with the canonical base in l 2 and also for the complementability of the corresponding generated subspaces, usually called Rademacher chaos, are derived. The results obtained allow, in particular, to establish the unimprovability of the exponential integrability of functions from Rademacher chaos. Besides, it is shown that for spaces that are "close" to L ∞ , the systems considered, in contrast to the ordinary Rademacher system, do not possess the property of unconditionality. The degree of this non-unconditionality is explained in the space L ∞ .