Radial differentiation of chemical composition of cryogenic soils in the Chara river valley, north of Transbaikalia

Abstract

The subject of the study is the content of iron compounds and their radial differentiation in the profiles of cryogenic soils of the Chara River valley (Transbaikalia). The studied soils belong to post-pyrogenic permafrost gleyzems, the depths of the seasonal active‐layer of these soils are from 34 to 44 cm. Macronutrient concentrations, with the exception of Si, rarely exceed 5.0%, while the silicon content reaches 24.3%. Si is also characterized by removal from the upper part of soil profiles and accumulation in permafrost soil horizons. The highest concentrations are characteristic in the O horizons (Mg – 4.8 and Ca – 1.5 mg/kg) for a significant part of the macroelements. The trace elements, Sr and Zr are distributed vary contrastingly (from 5.0 to 29.7 and from 5.6 to 47.1 mg/kg). Values of the R coefficient from 0.3 to 0.9 indicate the initial stage of post-pyrogenic restoration of soil properties, and the active accumulation of Mg, Ca, Ti, Fe, Sr, and other elements in the upper part of oxidized-gley permafrost gleyzem observed in the profile is a sign of active restoration. The soils contain about 3.4% iron, which more than 60–75% is the silicate group of compounds (Feс). The moisture content of soils and the prevailing reducing environmental conditions contribute to the formation of monotonous distributions in their profiles, and in soils without signs of stable hydromorphism, permafrost horizons contain almost 2 times more Feox and Feextr.