The relative energy responses of three indigenously developed optically stimulated luminescence (OSL) phosphors in the disc form were studied in therapeutic photon and electron beams. Calibration in terms of absorbed dose was carried out in the dose range 5–500 cGy in 60Co gamma rays, high energy X‐rays, and electron beams used in radiotherapy. The combined standard uncertainty in the estimation of absorbed dose using these OSL discs (OSLDs) was 3.3%. Dose–response curves of these OSLDs in 60Co gamma rays, 6 and 10 MV (flat and unflat), 15 MV and 6 and 15 MeV electron beams were found to be linear. Furthermore, these OSLDs exhibited a relative energy‐dependent response for both photon and electron beams. The relative energy response correction factor for photon and electron beams were in the range 1.01–1.05 and 1.03–1.06, respectively.