Radiation effects on chemistry

Serne, R.J.

doi:10.1016/0013-7952(89)90020-3

Cited by 2 publications

(2 citation statements)

References 41 publications

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“…This gamma radiation induced oxidizing reaction was attributed t o the formation o f H202 , a powerful oxidizing agent i n concentration exceeding of M. These conflicting data indicate t h a t radiolysis effects are not completely known f o r a l l combinations o f electrolyte compositions. This conclusion i s supported by the results of a review o f radiolysis effects on solution chemistry conducted by Serne (1989).…”

Section: A 57 Radio1 Y S I Ssupporting

confidence: 69%

Feasibility Report on Criticality Issues Associated with Storage of K Basin Sludge in Tanks Farms

Vail¹

1997

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Section: A 57 Radio1 Y S I Ssupporting

confidence: 69%

Feasibility Report on Criticality Issues Associated with Storage of K Basin Sludge in Tanks Farms

Vail¹

1997

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“…One other general review of radiation effects on solution chemistry was found (Serne 1989) that also suggests the issue is far from being understood. Although specific radiolysis data for actual tank solutions do not exist, several cited references and Delegard's solubility data (1995) indicate that the radiolysis effects on plutonium in Hanford Site HLW solutions maintain reducing conditions relative to plutonium aqueous chemistry.…”

Section: -6mentioning

confidence: 99%

Fluid dynamics, particulate segregation, chemical processes, and natural ore analog discussions that relate to the potential for criticality in Hanford tanks

Barney¹

1996

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Abstract.'This rcport prcsmis an tu-depth review of the potmdal for nudcar critiulity to ucsur in Hmtord defense waste tanks during past. CU:UTTCII~ and future safe Storage and mintcnanCe operations The report also briefly discusses lhe potential impacts of proposed retrieval activities. altliaugh retrieval was not a main focus of smpe. Alter thorough review of fluid dynamic aspects that focus on partrcle segregation, cheinical aspects that focus on solubility and adsorption processes that might concentrate plutonium andlor aeparate plutonium from the neutron absorbers in the lank waste, and ore-body fomatioii and mining operatiuns, the interdiswplin.iry tcam has come to the Conclusion that there IS negligible risk of iluclear critically under existing storage conditions in Hanfurd Site underground wabtr storage tanks. Further, fbr the accident scenarios considered an accidental criticality 16 incredible.The executive summary and suiiimaries at the end of cach brcli~ii 111 which subshidial analyses, calculations or literature interprehtions were perfmncd pmvidc more detailed findings and suppolt tor these conclusions. TRAOEMARK DISCLAIMERReference herein to any specific c o m e r c i a 1 product, process, or ACKNOWLEDGHENTSThe authors wish t o thank Ed Lipke, Bob Cash, Dave Nyham, and e s p e c i a l l y Dave Bratzel o f Westinghouse Hanford Company f o r funding t h i s work and keeping us focused on t h e key objectives. We wish t o thank Don Alexander from t h e U.S. Department o f Energy, Richland Operations O f f i c e f o r i n t r o d u c i n g us t o t h e t e c h n i c a l issue and programmatic h i s t o r y . H i s i n s i g h t and p r e l i m i n a r y analyses gave us a good foundation from which t o venture forward. thank Joe Brothers from t h e P a c i f i c Northwest National Laboratory Program O f f i c e f o r g u i d i n g us on protocols, f o r being our l a i s o n t o t h e Westinghouse Hanford Company f i n a n c i a l and program groups, f o r being our advocate i n several programmatic meetings, and f o r reviewing t h e d r a f t document. r e l a t e d work, both published and drafts, and helped guide us t o o t h e r important l i t e r a t u r e o r issues. recognize John Lafemina, Reza Shekarriz, Jun Liu, B r i a n Rapko, Penny Colton, Jim Campbell, Greg Lumetta, Jack Ryan, and We wish t o acknowledge t h e s t i m u l a t i n g discussions t h a t we had w i t h outside consultants, o t h e r Hanford S i t e s t a f f members, and formal reviewers, who were o f t e n unknown t o us, b u t whose comments on d r a f t m a t e r i a l helped sharpen t h e f i n a l r e p o r t .( p r i v a t e consultant), Nabil Morcos (Idaho National Engineering Laboratory), Dick Vorehm (M. Chew & Associates), Wally Schulz (W23 Company), Roland F e l t , Carole Sohn, and Harry C a l l e y (U.S. Department o f Energy), Jess Greenborg, Lou Rodgers, and Alan Waltar (Westinghouse Hanford Company), Rob Tayloe ( B a t t e l l e Columbus) and Andy Prichard ( P a c i f i c Northwest National Laboratory...

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Radiation effects on chemistry

Cited by 2 publications

References 41 publications

Feasibility Report on Criticality Issues Associated with Storage of K Basin Sludge in Tanks Farms

Feasibility Report on Criticality Issues Associated with Storage of K Basin Sludge in Tanks Farms

Fluid dynamics, particulate segregation, chemical processes, and natural ore analog discussions that relate to the potential for criticality in Hanford tanks

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