We show that the high energy limit for amplitude of the double electron capture to the bound state of the Coulomb field of a nucleus with emission of a single photon is determined by behavior of the wave function in the vicinity of the singular triple coalescence point. PCAC: 31.25.Eb; It is well known that the solution Ψ(r 1 , r 2 ) of the Schrödinger equation for a two-electron system in the Coulomb field of infinitely heavy point nucleus is singular at the triple coalescence point r 1 = r 2 = 0 [1, 2, 3, 4]. The wave function can be presented as a generalized power series containing logarithmic terms. The behavior of Ψ(r 1 , r 2 ) near this point is not very important in calculations of the binding energy since the corresponding phase volume is small. On the contrary it becomes crucial for calculation of the local energy E(r 1 , r 2 ) = HΨ(r 1 , r 2 )/Ψ(r 1 , r 2 ) [4]. However the triple coalescence point did not manifest itself in a dynamical process until now.In this letter we present an observable effect for the first time in which the interesting behavior of the two electron wave function Ψ(r 1 , r 2 ) near the point r 1 = r 2 = 0 (as well as that near the double coalescence points r 1 = 0 and r 2 = 0) plays an important role. For that we consider the double electron capture followed by the emission of a single photon in the high energy limit. Since the first attempts to detect this process in collisions of a light atom with a heavy nucleus [5] a number of experimental [6,7] and theoretical [8,9,10] papers were devoted to this reaction.Neglecting the internal motion of the electrons in the light atom we consider the capture of two continuum electrons with equal linear momenta p 1 = 1