2014
DOI: 10.1021/ma501555n
|View full text |Cite
|
Sign up to set email alerts
|

Radical Alternating Copolymerization of Twisted 1,3-Butadienes with Maleic Anhydride as a New Approach for Degradable Thermosetting Resin

Abstract: We report a novel approach for the synthesis of a readily curable and degradable resin by the radical alternating copolymerization of 1,3-diene monomers with maleic anhydride. 2,4-Dimethyl-1,3-pentadiene predominantly produced an alternating copolymer rather than a Diels–Alder adduct during the reaction with maleic anhydride. We revealed the most stable conformation as a twisted diene structure of 2,4-dimethyl-1,3-pentadiene and the other methyl-substituted dienes by DFT calculations, while a completely planar… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1

Citation Types

3
47
1
1

Year Published

2015
2015
2022
2022

Publication Types

Select...
6
1

Relationship

3
4

Authors

Journals

citations
Cited by 32 publications
(52 citation statements)
references
References 73 publications
3
47
1
1
Order By: Relevance
“…The determined monomer reactivity ratios are summarized in Table 2 . Highly alternating copolymerization behavior was confirmed by r 1 and r 2 values close to zero for the all copolymerization systems, being similar to the cases of MAn and diene monomers …”
Section: Resultssupporting
confidence: 60%
See 3 more Smart Citations
“…The determined monomer reactivity ratios are summarized in Table 2 . Highly alternating copolymerization behavior was confirmed by r 1 and r 2 values close to zero for the all copolymerization systems, being similar to the cases of MAn and diene monomers …”
Section: Resultssupporting
confidence: 60%
“…It is also noted that 1 H NMR spectra of the copolymers in Figure supported the predominant formation of 1,4‐repeating units for the diene monomers, as shown in Scheme . Large peaks observed at 5.0–5.1 ppm were assigned 1,4‐repeating units, and other peaks with a small intensity around the main peak were 1,2‐repeating one, being judged based on assignment for MAn/diene copolymers reported in the previous paper . The contents of 1,4‐repeating units were in a range of 85–88% for the copolymerization of RMIs with DMPD.…”
Section: Resultsmentioning
confidence: 86%
See 2 more Smart Citations
“…Nonetheless, the availability of structurally diverse anhydrides enables a wider variety of polymeric backbones for the obtained polyesters with potential applications in commodity materials [3] and biological materials [4]. Moreover, the use of unsaturated anhydride (such as MA et al) endows an exceptional advantage for new polymers [5] through further post-polymerization modification.…”
mentioning
confidence: 99%