2011
DOI: 10.1002/kin.20584
|View full text |Cite
|
Sign up to set email alerts
|

Radical copolymerization of fullerene (C60) and n‐butyl methacrylate (BMA) using triphenylbismuthonium ylide and characterization of C60–BMA copolymers

Abstract: Radical copolymerization of fullerene (C 60 ) and n-butyl methacrylate (BMA) has been carried out using triphenylbismuthonium ylide as an initiator at 70 • C for 4 h in a dilatometer under nitrogen atmosphere. The kinetic expression of the polymerization is R p α [Ylide] 0.5 [C 60 ] −1.0 [BMA] 1.2 , which is similar to that expected for ideal kinetics. The rate of polymerization increases with an increase in the concentration of initiator and BMA. However, it decreases with an increase in the concentration of… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
1
0

Year Published

2013
2013
2019
2019

Publication Types

Select...
3
1

Relationship

0
4

Authors

Journals

citations
Cited by 4 publications
(1 citation statement)
references
References 37 publications
0
1
0
Order By: Relevance
“…All copolymers have significantly different spectroscopic properties from both styrene and C 60 and show novel optical properties. Other free-radical copolymerizations of fullerenes with common monomers including styrene, , methyl methacrylate, ,,,, n -butyl methacrylate, 4-vinyl-benzoic acid, 2-cyanoethyl acrylate, and cyanovinyl acetate, have also been reported.…”
Section: Radical Scavenging Activity Of Fullerenes: Applications In P...mentioning
confidence: 99%
“…All copolymers have significantly different spectroscopic properties from both styrene and C 60 and show novel optical properties. Other free-radical copolymerizations of fullerenes with common monomers including styrene, , methyl methacrylate, ,,,, n -butyl methacrylate, 4-vinyl-benzoic acid, 2-cyanoethyl acrylate, and cyanovinyl acetate, have also been reported.…”
Section: Radical Scavenging Activity Of Fullerenes: Applications In P...mentioning
confidence: 99%