1990
DOI: 10.1021/ma00223a002
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Radical polymerization of N-(alkyl-substituted phenyl)maleimides: synthesis of thermally stable polymers soluble in nonpolar solvents

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Cited by 222 publications
(114 citation statements)
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“…13,18 The steric hindrance of the substituents in the ortho-substituted XPhMIs decreases their propagation rate constants and relative monomer reactivity during homo-and copolymerizations, respectively, according to the number and size of the substituents. 14,26,27 Consequently, alternating copolymers are readily produced during the copolymerization of the ortho-substituted XPhMIs with IB because of a lack of the homopolymerizability of IB. In the present study, the alternating copolymers of XPhMI and IB were obtained irrespective of the position of polar substituents in the phenyl group, during copolymerization under the conditions with a large excess of IB.…”
Section: Resultsmentioning
confidence: 99%
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“…13,18 The steric hindrance of the substituents in the ortho-substituted XPhMIs decreases their propagation rate constants and relative monomer reactivity during homo-and copolymerizations, respectively, according to the number and size of the substituents. 14,26,27 Consequently, alternating copolymers are readily produced during the copolymerization of the ortho-substituted XPhMIs with IB because of a lack of the homopolymerizability of IB. In the present study, the alternating copolymers of XPhMI and IB were obtained irrespective of the position of polar substituents in the phenyl group, during copolymerization under the conditions with a large excess of IB.…”
Section: Resultsmentioning
confidence: 99%
“…A similar behavior was also observed during the decomposition of the other poly(XPhMI-alt-IB)s with alkyl and alkoxycarbonyl substituents. 14,15 Poly(XPhMI-alt-IB)s containing hydroxy and carboxy groups showed the T g values of 222-232 C and 259 C, respectively, which are much higher than that of poly(1-alt-IB) (T g ¼ 186 C), as summarized in Table I. This result suggests that an increase in the T g values of poly(XPhMI-alt-IB)s is due to intermolecular hydrogen bonding between the hydroxy and carboxy groups.…”
Section: Resultsmentioning
confidence: 99%
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“…[1][2][3][4][5][6] The RMIs also copolymerize with electron-donating monomers, such as styrene, vinyl ethers, and olefins, to give alternating copolymers with excellent thermal stability and a high glass transition temperature (T g ). [7][8][9][10][11] Especially, the copolymerization of the RMIs with isobutene provided an alternating copolymer with excellent thermal stability, high transparency, and high modulus and strength.…”
Section: Introductionmentioning
confidence: 99%
“…The Q and e values for the BCPM monomer, calculated using the Alfrey and Price equation [55] are also included in Table 4 evident in ST systems reported in the literature [4, 6, 10, 56 -58]. The Q values for RMI calculated from the co-polymerization of RMI with ST are abnormal because of the formation of charge-transfer complexes [54]. The large e value correlates with strong electron acceptor nature of the maleimide monomer.…”
Section: Monomer Reactivity Ratiosmentioning
confidence: 99%