Radical telomerization of 3,3,3-trifluoro-1-propene by carbon tetrabromide. Individual chain transfer constants

Strategies for synthesizing non-bioaccumulable alternatives to PFOA and PFOS

“…Though the telomerizations of TFP with various chlorinated or brominated chain transfer agents were achieved by Vasil'eva et al [41][42][43][44] or Zamyslov et al [45,46], few works have been reported on the radical telomerization of TFP with perfluoroalkyliodides [47][48][49]. These telomers have further been chemically modified into cationic surfactants according to the strategy shown in Scheme 7.…”