Both AmAlO3 and PuAlO3 perovskites have been synthesized and characterized
using powder X-ray diffraction (XRD), Raman spectroscopy, Fourier
transform infrared spectroscopy (FT-IR), and 27Al magic
angle spinning nuclear magnetic resonance spectroscopy (MAS NMR).
AmAlO3 perovskite showed a rhombohedral configuration (space
group R3̅c) in agreement with
previous studies. The effect of americium α-decay on this material
has been followed by XRD and 27Al MAS NMR analyses. In
a first step, a progressive increase in the level of disorder in the
crystalline phase was detected, associated with a significant crystallographic
swelling of the material. In a second step, the crystalline AmAlO3 perovskite was progressively converted into amorphous AmAlO3, with a total amorphization occurring after 8 months and
2 × 1018 α-decays/g. For the first time, PuAlO3 perovskite was synthesized with an orthorhombic configuration
(space group Imma), showing an interesting parallel
to CeAlO3 and PrAlO3 lanthanide analogues. High-temperature
XRD was performed and showed a Imma → R3̅c phase transition occurring between
473 and 573 K. The thermal behavior of R3̅c PuAlO3 was followed from 573 to 1273 K, and
extrapolation of the data suggests that cubic plutonium perovskite
should become stable at around 1850 K (R3̅c → Pm3̅m transition).