Daily solar measurements of atmospheric absorption and atmospheric emission were conducted simultaneously for a period of nine months during 1967 and 1968. Nighttime observavations of emission followed daytime observations of absorption and emission. The month of June 1968, provided a fortuitous opportunity to observe absorption during rain since 23 out of 30 days had light to heavy rainfall. The brightness temperature of clouds was measured by the multi‐frequency instrument during the observation period. The observational frequencies of 8, 15, 19, and 35 GHz were used to determine the frequency correlation between meteorological phenomena and the atmospheric parameters associated with the fine structure characteristics of absorption and emission.