We investigate Higgs-radion mixing scenario through single radion photoproduction process pp → pγp → pRqX at the LHC. We consider high luminosity values of L int = 200 f b −1 , 500 f b −1 and 3000 f b −1 . We obtain bounds on the mixing parameter space by considering R → γγ, R → W + W − and R → ZZ decay channels of the radion as the signal. We also perform a similar analysis for a 100 TeV future proton-proton collider and compare its potential with that of LHC.