Raman spectrum of thiosaccharin

Baran, Enrique J.; Zinczuk, Juán

doi:10.1002/jrs.1503

Cited by 4 publications

(2 citation statements)

References 18 publications

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“…The assignment of some of the most characteris tic IR bands of the investigated compound is shown in Table 3. For comparative purposes we have also measured the spectrum of the free amine, and known data for the thiosaccharin molecule are also included [11,12], Standard references [13,14] were usedin the analysis and assignment of the spectra. Some aspects of the proposed assignments are commented as fol lows:…”

Section: Infrared Spectramentioning

confidence: 99%

“…99 %) and 0.11 mol of P2S5 (Merck) un der an N2 atmosphere, according to the procedure described by Meadow and Cavagnol [16], The reaction product was extracted with benzene and the crude orange-yellow product was recrystallized from benzene. Its purity was confirmed by the melting point (181-182 :C) and by IR and Raman spectra [11],…”

Section: Synthesis Of the Adductmentioning

confidence: 99%

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A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Hexamethylenediamine

Baran

Piro²,

Zinczuk³

2007

Zeitschrift Für Naturforschung B

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The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac)2 · 2H2O (tsac=C7H4NO2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules.

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Section: Infrared Spectramentioning

confidence: 99%

Section: Synthesis Of the Adductmentioning

confidence: 99%

A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Hexamethylenediamine

Baran

Piro²,

Zinczuk³

2007

Zeitschrift Für Naturforschung B

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Recent Advances in linear and nonlinear Raman spectroscopy I

Kiefer

2007

J Raman Spectroscopy

144

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Raman spectroscopy has advanced considerably in the last several years due to rapid developments in instrumentation and the availability of theoretical methods for accurate calculation of Raman spectra, thus enormously facilitating the interpretation of Raman data. This review is restricted to cover papers mainly published in the Journal of Raman Spectroscopy, which serve to give a fast overview of recent advances in this research field as well as to provide readers of this journal a quick introduction to the various subfields of Raman spectroscopy. It also reflects the current research interests of the Raman community. Similar reviews of highly active areas of Raman spectroscopy will appear in future issues of this journal.

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Vibrational properties, crystal X-ray diffraction structure and quantum chemical calculations on a divalent sulfur substituted phthalimide: 1H-Isoindole-1,3(2H)-dione, 2-[(methoxycarbonyl)thio]

Torrico-Vallejos¹,

Erben²,

Piro³

et al. 2010

Journal of Molecular Structure

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Raman spectrum of thiosaccharin

Abstract: The Raman spectrum of crystalline thiosaccharin was recorded and assigned by comparison with known IR spectroscopic data derived from experimental as well as theoretical studies.

Cited by 4 publications

References 18 publications

A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Hexamethylenediamine

A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Hexamethylenediamine

Recent Advances in linear and nonlinear Raman spectroscopy I

Vibrational properties, crystal X-ray diffraction structure and quantum chemical calculations on a divalent sulfur substituted phthalimide: 1H-Isoindole-1,3(2H)-dione, 2-[(methoxycarbonyl)thio]

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