Ultrasonic signal enhancement resulting from constructive interference between direct Rayleigh waves and same waves reflected by a surface defect is exploited to increase crack identification capabilities of the Gas-Coupled Laser Acoustic Detection (GCLAD) non-contact detection technology. Highlights from simulations are provided regarding the interference phenomenon in the solid and its propagation in air, where GCLAD detection occurs. Experimental campaigns are preliminarily performed on a bar to evidence the effect of cracks on the GCLAD acquired signals. Then, a signal enhancement of +30% is reached on a plate, implying that defects are efficiently scanned by moving the GCLAD in proximity of the discontinuity. Since the GCLAD allows monitoring points of a piece belonging to the same line at once, its translation in one direction is sufficient to perform a two-dimensional scan, entailing reduction of inspection time and simple automation of the interrogation layout compared to other traditional or signal enhancement-based techniques.