Ranking the Bronsted Acid Strength of Protonic Zeolites with VTIR Spectroscopy --- An Overview of Current Research

Abstract

Many industrial applications of protonic zeolites as solid-acid heterogeneous catalysts rely on the strength or their Br nsted acidity, which (together with zeolite topology) affects both, catalytic activity and selectivity. Therefore, the convenience to have an accurate (and simple) experimental technique for measuring Br nsted acid strength. The enthalpy change, Delta H0, corresponding to the hydrogen bonding interaction of a weak base (such as CO or dinitrogen) with their Br nsted acid [Si(OH)Al] hydroxyl groups should directly correlate with the zeolite acid strength. Nevertheless, because of simplicity, the bathochromic shift of the O-H stretching frequency, Deltaν(OH), is usually measured by IR spectroscopy at a low temperature, and correlated with acid strength, for ranking zeolite acidity. Herein the use of variable-temperature IR (VTIR) spectroscopy to determine simultaneously Delta H0 and Deltaν(OH) is demonstrated; followed by an abridged overview showing that direct correlation between Deltaν(OH) and Br.nsted acid strength can be misleading when ranking zeolite acidity. Keywords: VTIR spectroscopy, br nsted acidity, H-zeolites