Rapid and selective adsorption of Li+ from concentrated seawater using repulsive force of Al3+–crosslinked alginate composite incorporated with hydrogen manganese oxide

Park, Sung Ho; Yan, Yong‐Zhu; Kim, Jeongju; Ha, Chang‐Sik; Lee, Sang Joon

doi:10.1016/j.hydromet.2021.105812

Cited by 10 publications

(15 citation statements)

References 30 publications

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“…By using cryo-desiccation and cross-linking techniques, macroporous flexible foams were realized but their cycling abilities were inversely proportional to the loading amount of ion sieves into them. [88] Dried crosslinked alginate composites incorporated with HMO ion sieves were also recently reported by Park et al [56,126] In this case the selectivity of both the Al 3+ crosslinked alginated and the ion sieve powders were combined to recover lithium from concentrated seawater.…”

Section: Lmo-type Lismentioning

confidence: 73%

“…Uneven properties, time and energy consuming LMO [50][51][52][53][54][55][56] LTO [57][58][59][60][61][62][63][64][65][66][67][68][69] LMTO [70] LMO: 11.4 mg LTO [64,[76][77][78][79] LMO: 40 mg Sol-gel Good homogeneity, less time consuming, low calcination temperature Mostly suitable for nanoparticles LMO [74] LTO [62,80] LMO: 10 mg LTO [57][58][59][60]62,63,65,67,[76][77][78][82][83][84][85] LMO: 40 mg LTO [66,68,69] LMO: 10 mg LTO [64,80,…”

Section: Simple Operationmentioning

confidence: 99%

“…So far, no standard protocol to measure the selectivity of a process nor its recovery efficiency has been adopted. Several equa- Solid state Calcination [ 52,87,124,[227][228][229]238,239,257,258,282] Microwave combustion [48] Soft chemical Hydrothermal [71] Sol-gel [75] 𝛽-MnO 2 (Li 4 Mn 5 O 12 ) Solid state Calcination [55] Soft chemical Hydrothermal [50,53,129] H 1,6 Mn 1,6 O 4 Solid state Calcination [88,94] Soft chemical Hydrothermal [ 90,95,96] Sol-gel [74] H 1,33 Mn 1,67 O 4 Solid state Calcination [51,54,56,81,86,91] Soft chemical Hydrothermal [73] LTO H 2 TiO 3 layered [121,146] Solid state Calcination [57][58][59][60]62,63,[65][66][67]69,77,84,89] Soft chemical Hydrothermal…”

Section: Conclusion and Future Perspectivesmentioning

confidence: 99%

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Recent Advances in the Lithium Recovery from Water Resources: From Passive to Electrochemical Methods

et al. 2022

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The ever-increasing amount of batteries used in today's society has led to an increase in the demand of lithium in the last few decades. While mining resources of this element have been steadily exploited and are rapidly depleting, water resources constitute an interesting reservoir just out of reach of current technologies. Several techniques are being explored and novel materials engineered. While evaporation is very time-consuming and has large footprints, ion sieves and supramolecular systems can be suitably tailored and even integrated into membrane and electrochemical techniques. This review gives a comprehensive overview of the available solutions to recover lithium from water resources both by passive and electrically enhanced techniques. Accordingly, this work aims to provide in a single document a rational comparison of outstanding strategies to remove lithium from aqueous sources. To this end, practical figures of merit of both main groups of techniques are provided. An absence of a common experimental protocol and the resulting variability of data and experimental methods are identified. The need for a shared methodology and a common agreement to report performance metrics are underlined.

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Section: Lmo-type Lismentioning

confidence: 73%

Section: Simple Operationmentioning

confidence: 99%

Section: Conclusion and Future Perspectivesmentioning

confidence: 99%

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Recent Advances in the Lithium Recovery from Water Resources: From Passive to Electrochemical Methods

et al. 2022

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“…The synthetic strategy reported by Koilraj et al [73] is slightly different from that of Luo et al [24] and Li et al [72], where the later authors used Al-based LIS precursors relative to Mn-based precursor by Koilraj et al [73]. In another study, a novel strategy was employed to separate Li ions from concentrated seawater using a synergistic effect of Al 3+ -crosslinked ALG and hydrogen manganese oxide (HMO) [74]. The crosslinked Al 3+ in the ALG network structure generated a strong repulsive force to debar cations from competition with Li ions for adsorptive binding sites in the composite adsorbent.…”

Section: Metal-based Liss Granulated With Alginatementioning

confidence: 99%

Granulation of Lithium-Ion Sieves Using Biopolymers: A Review

Udoetok,

Karoyo,

Ubuo

et al. 2024

Polymers

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The high demand for lithium (Li) relates to clean, renewable storage devices and the advent of electric vehicles (EVs). The extraction of Li ions from aqueous media calls for efficient adsorbent materials with various characteristics, such as good adsorption capacity, good selectivity, easy isolation of the Li-loaded adsorbents, and good recovery of the adsorbed Li ions. The widespread use of metal-based adsorbent materials for Li ions extraction relates to various factors: (i) the ease of preparation via inexpensive and facile templation techniques, (ii) excellent selectivity for Li ions in a matrix, (iii) high recovery of the adsorbed ions, and (iv) good cycling performance of the adsorbents. However, the use of nano-sized metal-based Lithium-ion sieves (LISs) is limited due to challenges associated with isolating the loaded adsorbent material from the aqueous media. The adsorbent granulation process employing various binding agents (e.g., biopolymers, synthetic polymers, and inorganic materials) affords composite functional particles with modified morphological and surface properties that support easy isolation from the aqueous phase upon adsorption of Li ions. Biomaterials (e.g., chitosan, cellulose, alginate, and agar) are of particular interest because their structural diversity renders them amenable to coordination interactions with metal-based LISs to form three-dimensional bio-composite materials. The current review highlights recent progress in the use of biopolymer binding agents for the granulation of metal-based LISs, along with various crosslinking strategies employed to improve the mechanical stability of the granules. The study reviews the effects of granulation and crosslinking on adsorption capacity, selectivity, isolation, recovery, cycling performance, and the stability of the LISs. Adsorbent granulation using biopolymer binders has been reported to modify the uptake properties of the resulting composite materials to varying degrees in accordance with the surface and textural properties of the binding agent. The review further highlights the importance of granulation and crosslinking for improving the extraction process of Li ions from aqueous media. This review contributes to manifold areas related to industrial application of LISs, as follows: (1) to highlight recent progress in the granulation and crosslinking of metal-based adsorbents for Li ions recovery, (2) to highlight the advantages, challenges, and knowledge gaps of using biopolymer-based binders for granulation of LISs, and finally, (3) to catalyze further research interest into the use of biopolymer binders and various crosslinking strategies to engineer functional composite materials for application in Li extraction industry. Properly engineered extractants for Li ions are expected to offer various cost benefits in terms of capital expenditure, percent Li recovery, and reduced environmental footprint.

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“…Contrary to several reports on the use of organic and inorganic materials as binders for the granulation of metal-based LISs, reports on the use of biopolymers as binders are limited in the open literature (cf. Figure 4) [24,[49][50][51][52][53][54][71][72][73][74][75][76][77][78][79]. Additionally, there are currently no review articles that highlight the available knowledge gaps on the use of biopolymers as binders for the granulation of LISs.…”

Section: Granulation Of Liss Using Inorganic Materialsmentioning

confidence: 99%

Granulation of Lithium-Ion Sieves (LISs) Using Biopolymers: A Review

Udoetok,

Karoyo,

Ubuo

et al. 2024

Preprint

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The high demand for lithium (Li) relates to clean renewable storage devices and the advent of electric vehicles (EVs). The extraction of Li ions from aqueous media calls for efficient adsorbent materials with various characteristics, such as good adsorption capacity, good selectivity, easy isolation of the Li-loaded adsorbent, and good recovery of the adsorbed Li ions. The widespread use of metal-based adsorbent materials for Li ions extraction relates to various factors: (i) the ease of preparation via inexpensive and facile templation techniques, (ii) excellent selectivity for Li ions in a matrix, (iii) high recovery of the adsorbed ions, and (iv) good cycling performance of the adsorbents. However, the use of nano-sized metal-based LISs is limited due to challenges associated with isolating the loaded adsorbent material from the aqueous media. Adsorbent granulation process employing various binding agents (e.g., biopolymers, synthetic polymers, and inorganic materials) affords functional particles with modified morphological and surface properties that support easy isolation from the aqueous phase upon adsorption of Li ions. Biomaterials (e.g., chitosan, cellulose, alginate, and agar) are of particular interest because their structural diversity renders them amenable to coordination interactions with metal-based LISs to form 3D microcapsules. The current review highlights recent progress in the use of biopolymer binding agents for the granulation of metal-based LISs, along with various crosslinking strategies employed to improve the mechanical stability of the granules. The study reviews the effects of granulation and crosslinking on adsorption capacity, selectivity, isolation, recovery, cycling performance and the stability of the LISs. Adsorbent granulation using biopolymer binders has been reported to modify the uptake properties of the bio-adsorbent materials to varying degrees, in accordance with the surface and textural properties of the binding agent. The review further highlights the importance of granulation and crosslinking for improving the extraction process of Li ions from aqueous media. This review contributes to manifold areas related to industrial application of LISs, as follows: 1) to highlight recent progress in the granulation and crosslinking of metal-based adsorbents for Li ions recovery, 2) to highlight the advantages, challenges, and knowledge gaps of using biopolymer-based binders for granulation of LISs, and finally, 3) to catalyze further research interest into the use of biopolymer binders and various crosslinking strategies to engineer functional adsorbent materials for application in Li extraction industry. Properly engineered extractants for Li ions are expected to offer various cost benefits in terms of capital expenditure, percent Li recovery, and reduced environmental footprint.

show abstract

Rapid and selective adsorption of Li+ from concentrated seawater using repulsive force of Al3+–crosslinked alginate composite incorporated with hydrogen manganese oxide

Cited by 10 publications

References 30 publications

Recent Advances in the Lithium Recovery from Water Resources: From Passive to Electrochemical Methods

Recent Advances in the Lithium Recovery from Water Resources: From Passive to Electrochemical Methods

Granulation of Lithium-Ion Sieves Using Biopolymers: A Review

Granulation of Lithium-Ion Sieves (LISs) Using Biopolymers: A Review

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