“…[22][23][24] Thus, developing high-performing catalysts for concurrently promoting the NORR and inhibiting the HER is urgently required. [25][26][27][28][29] Transition metal diboride (TMB 2 )-based materials (TiB 2 , ZrB 2 , FeB 2 , MoB 2 , etc.) have been deemed promising candidates for N-cycle electrocatalysis due to their appealing capability to effectively activate nitrogenous molecules and show moderate intermediate binding energies to lower reaction energy barriers, [30][31][32][33][34] making TMB 2 a new class of NORR catalysts.…”