The separation and detection of compound orbital angular momentum (OAM) modes are the basis for achieving high-speed and high-capacity communication, but the atmospheric turbulence causes distortion of the phase fronts of vortex beams, which hinders the recognition of OAM modes. To solve this problem, in this work, we propose and investigate a joint scheme of combining the Gerchberg–Saxton (GS) algorithm and the phase of addition and subtraction model that can achieve high recognition accuracy and a wide range of OAM modes of compound perfect optical vortex beam under long-distance turbulence environment. At the receiving end, the GS algorithm and phase addition and subtraction are used to compensate and modulate the incident vortex light field to obtain the pre-processed light field, and then the OAM is detected by the coordinate transformation method. The simulation results show that: The detection range of the OAM of the three optical path detection model for the vortex beam transmitting 1000 m reaches −37 to +37 in the vacuum environment, and the mode purity of −37 to +37 can reach more than 0.3 when the turbulence intensity is Cn
2 = 2 × 10−15 m−2/3. The detection range of the OAM of the vortex can be further expanded by increasing the optical path. This study provides a new method for the separation and detection of OAM of composite vortex beams.