2015
DOI: 10.13005/ojc/310449
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Rapid Kinetics and Relative Reactivity of Some Five Membered Aromatic Heterocycles using Hydrodynamic Voltammetry

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“…Imidazole, pyrazole, and thiazole are five‐membered aromatic heterocycles with two heteroatoms. Rate constants for the bromination of imidazole, pyrazole and thiazole by molecular bromine are reported as 88.63, 75.52, and 18.63 M −1 s −1 , respectively 9 . Thiazole contains sulfur as the heteroatom, which reduces the basicity of the thiazole ring more than imidazole and pyrazole 28 .…”
Section: Resultsmentioning
confidence: 99%
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“…Imidazole, pyrazole, and thiazole are five‐membered aromatic heterocycles with two heteroatoms. Rate constants for the bromination of imidazole, pyrazole and thiazole by molecular bromine are reported as 88.63, 75.52, and 18.63 M −1 s −1 , respectively 9 . Thiazole contains sulfur as the heteroatom, which reduces the basicity of the thiazole ring more than imidazole and pyrazole 28 .…”
Section: Resultsmentioning
confidence: 99%
“…Rate constants for the bromination of imidazole, pyrazole and thiazole by molecular bromine are reported as 88.63, 75.52, and 18.63 M −1 s −1 , respectively. 9 sulfur as the heteroatom, which reduces the basicity of the thiazole ring more than imidazole and pyrazole. 28 Thiazole ring has larger d-electron delocalization and possesses greater aromaticity than imidazole and pyrazole.…”
Section: Relative Reactivity Of Substrates and Reagentsmentioning
confidence: 99%
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