2023
DOI: 10.1002/anie.202302739
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Rapid Phase Transitions of Thermotropic Glycolipid Quasicrystal and Frank‐Kasper Mesophases: A Mechanistic Rosetta Stone

Abstract: Experimental results are presented that serve to lower the barrier for developing the science and technology of non-classical thermotropic glycolipid mesophases, which now include dodecagonal quasicrystal (DDQC) and Frank-Kasper (FK) A15 and σ mesophases that can be produced under mild conditions from a versatile class of sugar-polyolefin conjugates. By employing "alloys" comprised of mono-and disaccharide-polyolefin conjugates, and optionally with vitamin E as a small molecule phase modulator, we report the s… Show more

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Cited by 8 publications
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