Rare earth benzene tetraanion-bridged amidinate complexes

Abstract

The benzene tetraanion-bridged rare earth inverse arene amidinate complexes [{Ln(κ1:η6-Piso)}2(μ-η6:η6-C6H6)] (2-Ln, Ln = Gd, Tb, Dy, Y; Piso = {(NDipp)2CtBu}, Dipp = C6H3iPr2-2,6) were prepared by the reduction of parent...