Rare earth transition metal plumbides—An update

Klenner, Steffen; Pöttgen, Rainer

doi:10.1016/bs.hpcre.2020.06.001

Cited by 6 publications

(2 citation statements)

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“…For better visibility, only one layer is presented in Figure . A more detailed crystal chemical discussion is given in references and . The striking feature of this plumbide is the Shastry–Sutherland-like substructure of the ytterbium atoms, which gives rise to magnetic frustration (discussed in detail in the magnetic part, vide infra).…”

Section: Selected Crystal Structuresmentioning

confidence: 99%

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On the Ytterbium Valence and the Physical Properties in Selected Intermetallic Phases

Engel,

Gießelmann,

Reimann

et al. 2024

ACS Org. Inorg. Au

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The present review summarizes important aspects of the crystal chemistry of ytterbium-based intermetallic compounds along with a selection of their outstanding physical properties. These originate in many cases from the ytterbium valence. Different valence states are possible here, divalent (4f 14 ), intermediate-valent, or trivalent (4f 13 ) ytterbium, resulting in simple diamagnetic, Pauli or Curie−Weiss paramagnetic, or valence fluctuating behavior. Especially, some of the Yb 3+ intermetallics have gained deep interest due to their Kondo or heavy Fermion ground states. We have summarized their property investigations using magnetic and transport measurements, specific heat data, NMR, ESR, and Mossbauer spectroscopy, elastic and inelastic neutron scattering, and XAS data as well as detailed thermoelectric measurements.

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Section: Selected Crystal Structuresmentioning

confidence: 99%

“…All these property studies were supported by quantum chemical calculations for a better understanding of the structure− property relationships. The complete property data of Yb 2 Pt 2 Pb has recently been reviewed, 87 and we refer to this broad overview for more details.…”

Section: Further Ternary Compoundsmentioning

confidence: 99%