Carbon monoxide (CO) is widely used as a tracer of molecular hydrogen (H 2 ) in metalrich galaxies, but is known to become ineffective in low metallicity dwarf galaxies. Atomic carbon has been suggested as a superior tracer of H 2 in these metal-poor systems, but its suitability remains unproven. To help us to assess how well atomic carbon traces H 2 at low metallicity, we have performed a series of numerical simulations of turbulent molecular clouds that cover a wide range of different metallicities. Our simulations demonstrate that in star-forming clouds, the conversion factor between [CI] emission and H 2 mass, X CI , scales approximately as X CI ∝ Z −1 . We recover a similar scaling for the CO-to-H 2 conversion factor, X CO , but find that at this point in the evolution of the clouds, X CO is consistently smaller than X CI , by a factor of a few or more. We have also examined how X CI and X CO evolve with time. We find that X CI does not vary strongly with time, demonstrating that atomic carbon remains a good tracer of H 2 in metal-poor systems even at times significantly before the onset of star formation. On the other hand, X CO varies very strongly with time in metal-poor clouds, showing that CO does not trace H 2 well in starless clouds at low metallicity.