2007
DOI: 10.1021/cg070468e
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Rational Construction of Porous Polymeric Cadmium Ferrocene-1,1′-disulfonates for Transition Metal Ion Exchange and Sorption

Abstract: Porous pillared bilayer open coordination polymer {[Cd(bpp) 2 (O 3 SFcSO 3 )] • (CH 3 OH) 2 • (H 2 O) 6 } n 1 (Fc ) ferrocene) and 3D porous coordination polymer {[Cd(bpy) 2 (O 3 SFcSO 3 )] • (CH 3 OH) 4 } n 2 have been assembled from Cd(NO 3 ) 2 , ferrocene-1,1′disulfonate, and bridging ligands 1,3-bis(4-pyridyl)propane (bpp) or 4,4′-bipyridine (bpy). Both of them show very special adsorption properties to copper salts. Along with the increase in the solution concentration of Cu(NO 3 ) 2 , the percentage of a… Show more

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Cited by 111 publications
(41 citation statements)
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“…Our previous investigations [21][22][23][24][25] indicate that the ion exchange reaction mechanism can be classified into two kinds. One is solid-state diffusion mechanism [26,27] with a nonhomogeneous phase exchange process.…”
mentioning
confidence: 99%
“…Our previous investigations [21][22][23][24][25] indicate that the ion exchange reaction mechanism can be classified into two kinds. One is solid-state diffusion mechanism [26,27] with a nonhomogeneous phase exchange process.…”
mentioning
confidence: 99%
“…The design and construction of metal-organic coordination polymers has been shown to be apromising field, not only because of their potential applications as functional solid materials in ion exchange,catalysis,luminescence, magnets, nonlinear optics, and gass eparation/storage [1][2][3][4][5][6]…”
Section: Discussionmentioning
confidence: 99%
“…The design and construction of metal-organic coordination polymers has been shown to be apromising field, not only because of their potential applications as functional solid materials in ion exchange,catalysis,luminescence, magnets, nonlinear optics, and gass eparation/storage [1][2][3][4][5][6].A mong various organic ligands, rodlike N,N'-donor building blocks, such as the conventionally employed 4,4'-bipyridine (bipy),a re widely employed to construct such coordination polymers [3,[7][8][9][10][11]. [Ag(m 2 -bipy)] + complexes have been extensively studied in coordination chemistry [12][13][14][15].…”
Section: Discussionmentioning
confidence: 99%
“…[16] The complex exhibits a strong attachment to water molecules, because the partially dehydrated crystal of 1 can rehydrate spontaneously and rapidly in air to the nascent state with identical cell parameters to thos of the assynthesized 1. Further the amorphous sample of 1 can be regenerated by water to the crystalline material again.…”
Section: Discussionmentioning
confidence: 99%