Rational Construction of Wide Coordination Space and Control of Adsorption Properties in One-Dimensional Cu(II) Coordination Polymer

Noro, Shin Ichiro; Fukuhara, Katsuo; Kubo, Kazuya; Nakamura, Takayoshi

doi:10.1021/cg2001392

Cited by 29 publications

(11 citation statements)

References 41 publications

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“…Introduction of Cu II ions in the same dimer motif was also achieved by the synthetic methods used for complexes 15 and 16 to give a PtCu‐heterometallic dimeric complex, syn ‐[PtCu(pyt) 2 (bpy) 2 ](PF 6 ) 2 ( syn ‐ 17 ) 56. The Cu II ion has a d 9 electronic configuration and can weakly bind (i.e., Jahn–Teller effect) additional ligands in the axial position, which is expected to act as a flexible guest‐binding site (Figure 20, a) 68–72. X‐ray crystallographic analysis for solvated syn ‐ 17 crystals clearly indicates that solvated molecules (CH 3 CN, acetone, and methanol) are coordinated in the axial position of the Cu II center.…”

Section: Bridging Ligand To Form Ptii‐containing Multinuclear Clusmentioning

confidence: 99%

Vapochromic Platinum(II) Complexes: Crystal Engineering toward Intelligent Sensing Devices

2014

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Vapochromic materials that show reversible color change driven by vapor adsorption/desorption have drawn significant attention because of their potential applications in chemical sensors and chemical‐switching modules. Among the vapochromic coordination complexes reported so far, a series of square‐planar PtII complexes has been studied and represents one of the most promising systems for practical chemical sensors. For such systems, the color of the complexes strongly depends not only on the ligand‐field splitting, but also on the intermolecular distance between the PtII ions. This microreview presents recent results of vapochromic complexes centered on one‐dimensionally stacked PtII systems from the viewpoint of the origin of their vapochromic behavior. The design of vapochromic materials has been facilitated because several useful chromophores, including metallophilic interaction between PtII ions, have been developed. However, it is still challenging to realize a specifically sensitive and selective response to targeted vapors. This review focuses on strategies to achieve assembled PtII complexes with selective vapochromic responses.

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Section: Bridging Ligand To Form Ptii‐containing Multinuclear Clusmentioning

confidence: 99%

Vapochromic Platinum(II) Complexes: Crystal Engineering toward Intelligent Sensing Devices

2014

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“…These changes are attributed to a shortening of the distance between the paramagnetic Cu II ion and the fluorine atom of an almost isotropically rotating PF 6 − anion . The ATR‐IR spectra show the splitting of a PF 6 − ν 3 vibration band around 830 cm −1 and the appearance of a formerly forbidden PF 6 − ν 1 vibration band at 740 cm −1 after the removal of acetone because of a lower anion symmetry . These experimental results suggest that the originally uncoordinated PF 6 − anions weakly coordinate to the open axial Cu II sites formed after removal of acetone molecules, as illustrated in Scheme .…”

Section: Resultsmentioning

confidence: 76%

“…These results indicate the integrity of the framework under high humidity. We have previously measured the H 2 O adsorption/desorption isotherms for [Cu(PF 6 ) 2 (bpetha) 2 ] n (bpetha=1,2‐bis(4‐pyridyl)ethane), which has a similar one‐dimensional structure to 1 , in which gate adsorption at P / P 0 is approximately 0.8 and large hysteresis were observed (Figure S21) . The bpp ligand has one more −CH 2 − than bpetha, which increases the hydrophobicity of 1 .…”

Section: Resultsmentioning

confidence: 99%

High CO₂/CH₄ Selectivity of a Flexible Copper(II) Porous Coordination Polymer under Humid Conditions

et al. 2015

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The development of highly efficient CO2 separation materials is very important for environmental preservation and energy conservation. Crystalline porous coordination polymers (PCPs)/metal–organic frameworks are one of a number of promising types of porous materials for CO2 separation because of their controllable pore size, shape and surface function. Simultaneously, the unique structural flexibility of PCPs affords both high CO2 selectivity and inexpensive regeneration. However, this family of materials suffers from the coexistence of water that destroys the framework of PCPs and its adsorption in the pores is greater than that of CO2, which results in a deterioration in CO2‐separation performance. Herein, a flexible and hydrophobic CuII PCP that is stable towards water has been designed and synthesised. This PCP has extremely high adsorption selectivity for CO2 over CH4, derived from its structural flexibility. Furthermore, the obtained water‐tolerant flexible PCP, under CO2/CH4 mixed‐gas conditions, exhibits highly selective CO2 adsorption over CH4, even in the presence of water.

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“…[1][2][3][4][5][6][7][8] And then a number of compounds or materials owning special properties were synthesized by rare-earth metals integrated with organic cations. They had been widely applied in optics, magnetics, catalysis, and analysis from 1980s.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Structures, and Properties of {(BDMLP)₂[Pb₂I₈]} and {(MLDE)[PbI₃]} Induced by N-Containing Organic Cation Templates

Wang

et al. 2015

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-

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Two new cation-templated complexes, (BDMLP) 2 [Pb 2 I 8 ]} (1) and {(MLDE)[PbI 3 ]}n (2) [BDMLP D 1,3-bis(dimethylimidazole) propane; MLDE D methylimidazole ethane] have been synthesized via the self-assembly reaction in solution. Single-crystal X-ray diffraction analysis shows compound 1 is a dimer and 2 is a 1D chain. Electrostatic interactions between the organic counteranions and inorganic moieties are present and do the contribution to the crystal packing. These compounds have been further characterized by IR, fluorescence spectrophotometer, and thermostability properties.

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Rational Construction of Wide Coordination Space and Control of Adsorption Properties in One-Dimensional Cu(II) Coordination Polymer

Cited by 29 publications

References 41 publications

Vapochromic Platinum(II) Complexes: Crystal Engineering toward Intelligent Sensing Devices

Vapochromic Platinum(II) Complexes: Crystal Engineering toward Intelligent Sensing Devices

High CO₂/CH₄ Selectivity of a Flexible Copper(II) Porous Coordination Polymer under Humid Conditions

Synthesis, Structures, and Properties of {(BDMLP)₂[Pb₂I₈]} and {(MLDE)[PbI₃]} Induced by N-Containing Organic Cation Templates

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Rational Construction of Wide Coordination Space and Control of Adsorption Properties in One-Dimensional Cu(II) Coordination Polymer

Cited by 29 publications

References 41 publications

Vapochromic Platinum(II) Complexes: Crystal Engineering toward Intelligent Sensing Devices

Vapochromic Platinum(II) Complexes: Crystal Engineering toward Intelligent Sensing Devices

High CO2/CH4 Selectivity of a Flexible Copper(II) Porous Coordination Polymer under Humid Conditions

Synthesis, Structures, and Properties of {(BDMLP)2[Pb2I8]} and {(MLDE)[PbI3]} Induced by N-Containing Organic Cation Templates

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Product

Resources

About

High CO₂/CH₄ Selectivity of a Flexible Copper(II) Porous Coordination Polymer under Humid Conditions

Synthesis, Structures, and Properties of {(BDMLP)₂[Pb₂I₈]} and {(MLDE)[PbI₃]} Induced by N-Containing Organic Cation Templates