Rational design of tapered multiblock copolymers for thermoplastic elastomers

Steube, Marvin; Johann, Tobias; Barent, Ramona D.; Müller, Axel H. E.; Frey, Holger

doi:10.1016/j.progpolymsci.2021.101488

Cited by 75 publications

(87 citation statements)

References 298 publications

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“…TPE is a new class material that combines the vulcanized properties of rubber with the ability to simplify thermoplastic processes [175]. Elastomers and thermoplastics help in their mixing for the strengthening of the material.…”

Section: Thermoplastic Elastomer Enr/pvc Blendsmentioning

confidence: 99%

Natural Fiber-Reinforced Thermoplastic ENR/PVC Composites as Potential Membrane Technology in Industrial Wastewater Treatment: A Review

et al. 2022

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Membrane separation processes are prevalent in industrial wastewater treatment because they are more effective than conventional methods at addressing global water issues. Consequently, the ideal membranes with high mechanical strength, thermal characteristics, flux, permeability, porosity, and solute removal capacity must be prepared to aid in the separation process for wastewater treatment. Rubber-based membranes have shown the potential for high mechanical properties in water separation processes to date. In addition, the excellent sustainable practice of natural fibers has attracted great attention from industrial players and researchers for the exploitation of polymer composite membranes to improve the balance between the environment and social and economic concerns. The incorporation of natural fiber in thermoplastic elastomer (TPE) as filler and pore former agent enhances the mechanical properties, and high separation efficiency characteristics of membrane composites are discussed. Furthermore, recent advancements in the fabrication technique of porous membranes affected the membrane’s structure, and the performance of wastewater treatment applications is reviewed.

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Section: Thermoplastic Elastomer Enr/pvc Blendsmentioning

confidence: 99%

Natural Fiber-Reinforced Thermoplastic ENR/PVC Composites as Potential Membrane Technology in Industrial Wastewater Treatment: A Review

et al. 2022

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“…Compared with one-and two-segment polymers, multisegmented ATPs with more desirable properties depending on chemical compositions and macromolecular parameters can hold great promise in multipurpose applications. [24][25][26][27][28][29][30][31] Among them, linker-reactive multisite multisegmented polymers (LMMPs) with linear or nonlinear architectures are an important subclass of ATPs. [8][9][10][11][16][17][18][19][27][28][29][30][31][32][33][34][35][36][37] Owing to multiple functionalities and variable segment numbers, they can exhibit some interesting features and unique properties.…”

Section: Introductionmentioning

confidence: 99%

“…[24][25][26][27][28][29][30][31] Among them, linker-reactive multisite multisegmented polymers (LMMPs) with linear or nonlinear architectures are an important subclass of ATPs. [8][9][10][11][16][17][18][19][27][28][29][30][31][32][33][34][35][36][37] Owing to multiple functionalities and variable segment numbers, they can exhibit some interesting features and unique properties. First, the reactive sites present in neighboring polymer segments can endow LMMPs with versatile topological transformations via coupling, cleavage and polymerization.…”

Section: Introductionmentioning

confidence: 99%

Rational design of a multi-in-one heterofunctional agent for versatile topological transformation of multisite multisegmented polystyrenes

et al. 2022

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“…In most cases, the blocks are thermodynamically incompatible, but the covalent bonds between them lead to interactions, creating certain morphologies both in bulk and in solution. This behavior is a consequence of microphase separation caused by the thermodynamic incompatibility of the blocks [1][2][3][4][5][6][7][8][9][10][11].…”

Section: Introductionmentioning

confidence: 99%

Optically Transparent Polydimethylsiloxane-Ethylene Oxide-Propylene Oxide Multiblock Copolymers Crosslinked with Isocyanurates as Organic Compound Sorbents

et al. 2022

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New crosslinked (polydimethylsiloxane-ethylene-propylene oxide)-polyisocyanurate multiblock copolymers (MBCs) were synthesized, and their supramolecular structure and sorption characteristics were studied. It was found that the interaction of PPEG and D4 leads to polyaddition of D4 initiated by potassium-alcoholate groups. The use of the amphiphilic silica derivatives associated in an oligomeric medium (ASiPs) leads to structuring of the MBC due to the transetherification reaction of the terminal silanol groups of the MBC with ASiPs. It was established that the supramolecular structure of an MBC is built according to the “core-shell” structure. The obtained polymers were tested as sorbents for the development of new methods for the concentration and determination of inorganic compounds. The efficiency of sorption of reagents increased with an increase in the “thickness” of the polydimethylsiloxane component of the “shell” and with a decrease in the size of the polyisocyanurate “core”. The use of the obtained polymers as adsorbents of organic reagents is promising for increasing the efficiency of field methods of chemical testing and inorganic analysis, including the determination of the elemental composition and the detection of traces of contamination.

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Rational design of tapered multiblock copolymers for thermoplastic elastomers

Cited by 75 publications

References 298 publications

Natural Fiber-Reinforced Thermoplastic ENR/PVC Composites as Potential Membrane Technology in Industrial Wastewater Treatment: A Review

Natural Fiber-Reinforced Thermoplastic ENR/PVC Composites as Potential Membrane Technology in Industrial Wastewater Treatment: A Review

Rational design of a multi-in-one heterofunctional agent for versatile topological transformation of multisite multisegmented polystyrenes

Optically Transparent Polydimethylsiloxane-Ethylene Oxide-Propylene Oxide Multiblock Copolymers Crosslinked with Isocyanurates as Organic Compound Sorbents

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