As is well known, energy levels appearing in the highly degenerate spectra of the A N´1 type of Haldane-Shastry and Polychronakos spin chains can be classified through the motifs, which are characterized by some sequences of the binary digits like '0' and '1'. In a similar way, at present we classify all energy levels appearing in the spectra of the BC N type of Polychronakos spin chains with Hamiltonians containing supersymmetric analogue of polarized spin reversal operators. To this end, we show that the BC N type of multivariate super Rogers-Szegö (SRS) polynomials, which at a certain limit reduce to the partition functions of the later type of Polychronakos spin chains, satisfy some recursion relation involving a q-deformation of the elementary supersymmetric polynomials. Subsequently, we use a Jacobi-Trudi like formula to define the corresponding q-deformed super Schur polynomials and derive a novel expression for the BC N type of multivariate SRS polynomials as suitable linear combinations of the q-deformed super Schur polynomials. Such an expression for SRS polynomials leads to a complete classification of all energy levels appearing in the spectra of the BC N type of Polychronakos spin chains through the 'branched' motifs, which are characterized by some sequences of integers of the form pδ 1 , δ 2 , ..., δ N´1 |lq, where δ i P t0, 1u and l P t0, 1, ..., Nu. Finally, we derive an extended boson-fermion duality relation among the restricted super Schur polynomials and show that the partition functions of the BC N type of Polychronakos spin chains also exhibit similar type of duality relation.