We study Hecke algebras for pairs (g, K) over arbitrary fields E of characteristic 0, define the Bernstein functor and give another definition of the Zuckerman functor over E. Building on this and the author's previous work on rational structures on automorphic representations, we show that hard duality remains valid over E and apply this result to the study of rationality properties of Sun's cohomologically induced functionals. Our main application are period relations for the special values of standard L-functions of automorphic representations of GL(2n) admitting Shalika models.