Rationally designed carbon-encapsulated manganese selenide composites from metal–organic frameworks for stable aqueous Zn–Mn batteries

Wang, Bin; Li, Wenqi; Wang, Siyuan; Xie, Peng; Wan, Peng; Gui, Ying; Chen, Ding

doi:10.1039/d3ta08043a

J. Mater. Chem. A

2024

DOI: 10.1039/d3ta08043a

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Rationally designed carbon-encapsulated manganese selenide composites from metal–organic frameworks for stable aqueous Zn–Mn batteries

Bin Wang,

Wenqi Li,

Siyuan Wang

et al.

Abstract: Aqueous zinc ion batteries (AZIBs) have emerged as promising candidates for large-scale energy storage and small electronic devices due to their environmentally friendly, safe, stable, and cost-effective characteristics. Among various...

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Cited by 2 publications

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Graphene-based composites as the cathodes for high-performance aqueous zinc-ion batteries: Applications and perspectives

Pei,

Liu,

Kong

et al. 2024

Chinese Chemical Letters

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Graphene-based composites as the cathodes for high-performance aqueous zinc-ion batteries: Applications and perspectives

Pei,

Liu,

Kong

et al. 2024

Chinese Chemical Letters

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Efficient Preparation of Metal-Ion Intercalated Vanadium-Based Cathodes for High-Performance Aqueous Zinc-Ion Batteries: Na₂V₆O₁₆·3H₂O as an Example

Xie,

Wang,

Chen

et al. 2024

ACS Appl. Mater. Interfaces

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The inherent challenges associated with aqueous zinc ion batteries (AZIBs), such as low energy density and slow diffusion kinetics, pose significant obstacles to their widespread adoption as energy storage systems. These limitations mainly stem from the nongreen and complex preparation process of high-quality cathode materials. In this study, we propose an approach utilizing microwave-assisted ball milling to expedite the fabrication of vanadium-based intercalated nanomaterials, aiming at solving the problem of prolonged reaction at high temperatures, which is unavoidable in the preparation of anode materials. Na 2 V 6 O 16 (NVO) nanorods were synthesized in just 40 min under aqueous solvent conditions. These nanorods exhibit remarkable electrochemical properties, including a high specific capacity of 564 mA h g −1 at 0.1 A g −1 and an excellent cycle life, maintaining 164.2 mA h g −1 after 5000 cycles at 5 A g −1 . Additionally, the incorporation of Na + into the electrolyte effectively mitigates the stripping of Na + and the deposition of Zn dendrimers from NVO, further contributing to enhanced cycling stability. The findings of this study offer a promising approach to the rapid and efficient synthesis of high-quality ZIB cathode materials. KEYWORDS: Microwave-assisted ball milling, Vanadium-based compound, Na 2 V 6 O 16 •3H 2 O, Aqueous zinc-ion batteries, Electrolyte control, High capacity

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Rationally designed carbon-encapsulated manganese selenide composites from metal–organic frameworks for stable aqueous Zn–Mn batteries

Abstract: Aqueous zinc ion batteries (AZIBs) have emerged as promising candidates for large-scale energy storage and small electronic devices due to their environmentally friendly, safe, stable, and cost-effective characteristics. Among various...

Cited by 2 publications

References 61 publications

Graphene-based composites as the cathodes for high-performance aqueous zinc-ion batteries: Applications and perspectives

Graphene-based composites as the cathodes for high-performance aqueous zinc-ion batteries: Applications and perspectives

Efficient Preparation of Metal-Ion Intercalated Vanadium-Based Cathodes for High-Performance Aqueous Zinc-Ion Batteries: Na₂V₆O₁₆·3H₂O as an Example

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Rationally designed carbon-encapsulated manganese selenide composites from metal–organic frameworks for stable aqueous Zn–Mn batteries

Abstract: Aqueous zinc ion batteries (AZIBs) have emerged as promising candidates for large-scale energy storage and small electronic devices due to their environmentally friendly, safe, stable, and cost-effective characteristics. Among various...

Cited by 2 publications

References 61 publications

Graphene-based composites as the cathodes for high-performance aqueous zinc-ion batteries: Applications and perspectives

Graphene-based composites as the cathodes for high-performance aqueous zinc-ion batteries: Applications and perspectives

Efficient Preparation of Metal-Ion Intercalated Vanadium-Based Cathodes for High-Performance Aqueous Zinc-Ion Batteries: Na2V6O16·3H2O as an Example

Contact Info

Product

Resources

About

Efficient Preparation of Metal-Ion Intercalated Vanadium-Based Cathodes for High-Performance Aqueous Zinc-Ion Batteries: Na₂V₆O₁₆·3H₂O as an Example