“…Metal phosphates have been used in metallurgy and pesticides since the 1960s, and their applications in diesel and gasoline hydrogenation, dehydrogenation, hydrodesulfurization, hydride nitration, and desulfurization have also received much attention. , Notably, the application of Ni 2 P in hydrogen evolution reaction (HER) was first reported by Liu and Rodriguez in 2005 and showed considerable H 2 activity . Since then, the application of TMPs in photocatalytic hydrogen production has become a hot research topic. , In hydrogen evolution reactions, most TMPs are used as co-catalysts to replace high-cost noble metals such as Pt, Ru, and Pd. , In addition, some TMPs are also used as main photocatalysts to provide electrons for hydrogen production …”