2021
DOI: 10.1002/chem.202101127
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Re‐entrant Photoinduced Morphological Transformation and Temperature‐Dependent Kinetic Products of a Rectangular Amphiphilic Diarylethene Assembly

Abstract: An amphiphilic rectangular-shaped photochromic diarylethene bearing two hydrophobic alkyl chains and two hydrophilic tri(ethylene glycol) chains was synthesized, and its photoinduced morphological transformation in water was investigated. Two unexpected phenomena were revealed in the course of the experiments: a re-entrant photoinduced macroscopic morphological transformation and temperaturedependent kinetic products of supramolecular assembly. When the pure closed-ring isomer was dispersed in water, a re-entr… Show more

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Cited by 2 publications
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