Reaction of 2-mercaptothiazoline with α-halogenocar bonyl compounds

2,3-Dihydrothiazolo[2,3- b ]thiazolium iodides and bromide were obtained for the first time by the cyclization of corresponding metallyl- and propinylsulfanyl derivatives of 1,3-thiazole with iodine and bromine in dichloromethane without heating and the use of strong acids. The structure of the obtained compounds was studied by 1H, 13C{1H} NMR spectroscopy. Structure of the 3-iodomethyl-3,5-dimethyl-2,3-dihydrothiazolo[2,3- b ][1,3]thiazolium heterocyclic system is characterized by the X-ray analysis. The bonding in the heterocyclic system and non-covalent cation-anion interactions are analyzed on the basis of quantum chemical calculations with periodic boundary conditions; I···S chalcogen bond is discussed.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Reaction of 2-mercaptothiazoline with α-halogenocar bonyl compounds

Cited by 2 publications

References 1 publication

Synthesis, Structure, and Non-Covalent Interactions of 5-Methyl-2,3-dihydrothiazolo[2,3-b]thiazolium Halides

Synthesis, Structure, and Non-Covalent Interactions of 5-Methyl-2,3-dihydrothiazolo[2,3-b]thiazolium Halides

Synthesis, structure and non-covalent interactions of 5-methyl-2,3-dihydrothiazolo[2,3-<i>b</i>]thiazolium halides

Contact Info

Product

Resources

About