Reaction of Fenchone Hydrazone with Diselenium Dibromide: Novel Formation of Bicyclic Diselenide

Carbonyl compounds were added to selenocarbamoyllithiums to generate α-hydroxy and α-oxo selenoamides. Their conformations were determined by X-ray analyses. These compounds adopted conformations that were almost identical to those of ordinary amides. Unlike the consistency of the chemical shifts of the C═Se groups of the selenoamides in (13)C NMR spectra and the (1)J coupling constants of the C═Se groups, the substituents far from the selenium atom influenced the chemical shifts in (77)Se NMR.

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α-Hydroxy and α-Oxo Selenoamides: Synthesis via Nucleophilic Selenocarbamoylation of Carbonyl Compounds and Characterization

Murai

Mizutani

Ebihara

et al. 2015

J. Org. Chem.

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Neighboring Group Participation of Thiofenchone with Acyl Chlorides: Novel Formation of 2-Acyloxy-2,7,7-trimethylnorbornan-1-thiols

et al. 2017

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Synthesis of Nitrogen Containing Heterocycles by Using Carbon-Nitrogen Double Bond

Okuma¹

2018

HETEROCYCLES

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Reaction of Fenchone Hydrazone with Diselenium Dibromide: Novel Formation of Bicyclic Diselenide

Cited by 3 publications

References 18 publications

α-Hydroxy and α-Oxo Selenoamides: Synthesis via Nucleophilic Selenocarbamoylation of Carbonyl Compounds and Characterization

α-Hydroxy and α-Oxo Selenoamides: Synthesis via Nucleophilic Selenocarbamoylation of Carbonyl Compounds and Characterization

Neighboring Group Participation of Thiofenchone with Acyl Chlorides: Novel Formation of 2-Acyloxy-2,7,7-trimethylnorbornan-1-thiols

Synthesis of Nitrogen Containing Heterocycles by Using Carbon-Nitrogen Double Bond

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