Reaction of [Fluoro(trifluoromethylsulfonyloxy)iodo]benzene with Dimethyl exo‐3,4‐Epoxytricyclo [4.2.2.0^2,5]deca‐7,9‐diene‐9,10‐dicarboxylate.

Abstract

Bridged compoundsBridged compounds Q 0060 Reaction of [Fluoro(trifluoromethylsulfonyloxy)iodo]benzene with Dimethyl exo-3,4-Epoxytricyclo[4.2.2.0 2,5 ]deca-7,9-diene-9,10-dicarboxylate. -(PIRKULIEV, N. S.; MAGERRAMOV, A. M.; ALLAKHVERDIEV, M. A.; MIRBAGIROVA, G. M.; BREL', V. K.; ZEFIROV, N. S.; Russ.

Synthesis, structural characterization, reactivity and catalytic activity of mixed halo/triflate ArI(OTf)(X) species

“…Subsequent to these initial reports, PhIF(OTf ) and PhIF(OMs) have been used in synthetic applications several times by Zefirov including reactions with norbornene, 21 cyclic & acyclic olefins 20,22 and as a pathway to Weiss' reagents. [23][24][25] Stang's first report mentions that PhIF(OTf ) formed a [Ph-I-Ph-I] + [OTf ] − on exposure to iodobenzene, 17 demonstrating that PhIF(OTf ) decomposes via an EAS pathway to form this iodonium salt, explaining why PhIF(OMs) and PhIF(OTf ) were never characterized.…”

Synthesis, structural characterization, reactivity and catalytic activity of mixed halo/triflate ArI(OTf)(X) species

“…Again, this compound was not subject to characterization. Subsequent to these initial reports, PhIF(OTf) and PhIF(oMS) have been used in synthetic applications several times by Zefirov including reactions with norbornene, 19 cyclic & acyclic olefins 18,20 and as a pathway to Weiss' reagents. [21][22][23] Stang's first report mentions that PhIF(OTf) formed a [Ph-I-Ph-I] + [OTf]on exposure to iodobenzene, 16 demonstrating that PhIF(OTf) decomposes via an EAS pathway to form this iodonium salt, explaining why PhIF(oMS) and PhIF(OTf) were never characterized.…”