Reaction of N‐thioamido amidines with phosphoramide derivatives: Synthesis of 2‐substituted‐1,3,5,2‐triazaphosphorines

Investigating the Phosphine Chemistry of Se Precursors for the Synthesis of PbSe Nanorods

“…This section explores how free TDP in PbSe NR synthesis may play such an important role. Because the P−N bond of TDP is weaker than P−C bond of TOP, the P−N bond may easily cleave to give amine species under various conditions such as nucleophile attack or EI-MS ionization. − To confirm the release of amine, we monitored the decomposition of free phosphine in the TDPSe-based synthesis using TGA-MS. One M TDPSe in TDP solution shows a possible NEt 2 + peak ( m / z = 72) during the heating process, which can be from either the release of NEt 2 or the fragmentation of vaporized TDP above 150 °C (Figure a and b). Running the same experiment with neat TDPSe solution, TGA-MS produces the NE t 2 + peak at a higher temperature (above 220 °C) with much less ion intensity of mass decomposition than with 1 M TDPSe in TDP solution (Figure c,d).…”

Recent Advances in Organic Reactions Involving Elemental Sulfur

“…Phosphorus compounds containing N–P bonds 273 reacted in a similar manner with elemental sulfur (Scheme ) . Only small excess quantities of sulfur were required to obtain nearly quantitative yields of the expected P=S products 274 .…”