Reaction of polydimethylsiloxane macromolecules with iron compounds

Interaction of polyphenylsiloxane with magnesium acetylacetonate

“…Furthermore, the cleavage of the siloxane bond can occur under the action of phosphorus oxide or phosphoruscontaining acids [3] as well as of boric acid [4]. The interaction of iron acetylacetonate with polydimethylsiloxane in toluene is known to yield the product containing Si-O-Fe fragments [5]. The interaction of metal oxides with polyphenylsiloxane under conditions of mechanochemical activation has yielded (phenylmetal)siloxanes as well [6].…”