Phys. Chem. Chem. Phys.
 2024
DOI: 10.1039/d4cp02106a
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Reaction pathways leading to HPALD intermediates in the OH-initiated oxidation of isoprene

Péter Szabó,
Zhen Liu,
Jean-François Müller
et al.

Abstract: The HPALD formation in the OH-initiated isoprene oxidation has been revisited. Vibrationally hot peroxy radicals from O2 addition in the α-position of Z,Z′-OH-allyl radicals decompose in a chemically activated manner, efficiently yielding δ-HPALDs.

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