“…Scheme 25 The Bi(OTf) 3 -catalysed benzoylation of anisole under microwave (MW) irradiation led without temperature control to shorter reaction times due to the specific interaction of MW with the produced aryl ketone and especially with the catalystϪketone complex (Scheme 26). [53] Scheme 26…”
Bismuth(III) triflate is a new, cheap and environmentally friendly Lewis acid. The research presented in this microreview is devoted to the evaluation of the scope of the uses of bismuth(III) triflate in organic synthesis.
“…Scheme 25 The Bi(OTf) 3 -catalysed benzoylation of anisole under microwave (MW) irradiation led without temperature control to shorter reaction times due to the specific interaction of MW with the produced aryl ketone and especially with the catalystϪketone complex (Scheme 26). [53] Scheme 26…”
Bismuth(III) triflate is a new, cheap and environmentally friendly Lewis acid. The research presented in this microreview is devoted to the evaluation of the scope of the uses of bismuth(III) triflate in organic synthesis.
“…Solvent-free benzoylation of aromatic ethers has been performed under the action of microwave irradiation in the presence of a metallic catalyst, FeCl 3 being one of the most efficient [101]. With careful control of the temperature and other parameters, nonthermal microwave effects have not been observed either in terms of yields or isomeric ratios of the obtained products (Eq.…”
Section: Friedel±crafts Acylation Of Aromatic Ethersmentioning
“…Solvent-free benzoylation of aromatic ethers has been performed under the action of MW irradiation in the presence of a metallic catalyst, FeCl 3 being one of the most efficient [197]. The reactive species is the acylium ion resulting from abstraction of a chloride anion from benzoyl chloride [Eq.…”
Section: Friedel-crafts Acylation Of Aromatic Ethersmentioning
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