Reactions Involving Hetero Atoms

Kirmse, Wolfgang

doi:10.1016/b978-0-12-409956-2.50015-7

Carbene Chemistry 1971

DOI: 10.1016/b978-0-12-409956-2.50015-7

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Reactions Involving Hetero Atoms

Wolfgang Kirmse

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2017

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Crystal structure and DFT studies of 4-methyl-N-(1-phenylethyl)-N′-(1-phenylethylidene)benzenesulfono-hydrazide: evidence of a carbene insertion in the formation of acetophenone azine from acetophenone p-toluensulfonylhydrazone

et al. 2017

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The crystal structure of 4-Methyl-N-(1-phenylethyl)-N′-(1-phenylethylidene) benzene sulfonohydrazide is disclosed, which is obtained from direct reaction between acetophenone tosylhydrazone and potassium tert-butoxide. Reaction mechanisms and the corresponding energy barriers were assessed through DFT calculations at the B3LYP/6-31G(d,p) level of theory and showed that this compound plays an important role as an intermediate in the formation of acetophenone azine from acetophenone p-toluensulfonylhydrazone through a carbene insertion on this last compound.

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Crystal structure and DFT studies of 4-methyl-N-(1-phenylethyl)-N′-(1-phenylethylidene)benzenesulfono-hydrazide: evidence of a carbene insertion in the formation of acetophenone azine from acetophenone p-toluensulfonylhydrazone

et al. 2017

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Reactions Involving Hetero Atoms

Cited by 1 publication

References 244 publications

Crystal structure and DFT studies of 4-methyl-N-(1-phenylethyl)-N′-(1-phenylethylidene)benzenesulfono-hydrazide: evidence of a carbene insertion in the formation of acetophenone azine from acetophenone p-toluensulfonylhydrazone

Crystal structure and DFT studies of 4-methyl-N-(1-phenylethyl)-N′-(1-phenylethylidene)benzenesulfono-hydrazide: evidence of a carbene insertion in the formation of acetophenone azine from acetophenone p-toluensulfonylhydrazone

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