Reactions of ansa fluorodioxy cyclotriphosphazene derivatives with phenol

Designing inorganic–organic hybrid molecules based on carbazole/indole-appended cyclotriphosphazenes and the investigation of their photophysical properties

“…The P-N bond length, P-N-P and N-P-N bond angles are quite similar, and the results are compatible with those of previously synthesized cyclotriphosphazene derivatives. [52][53][54][55] Although the cyclotriphosphazene skeleton is a planar structure, it can deviate from planarity due to the substituents on it. Here, the ring is deviated from planarity due to the carbazole groups on it.…”

Chiral configurations in cyclophosphazene chemistry

“…It is not possible meso form for Type II(4), Type II(5), Type II(7) Type II (8) and Type II (9) configurations. Hence all derivatives would be racemates which are shown for Type II(5) cis (55* [64], 56a [93], 56b [82]), Type II(5) trans (57 [76]), Type II(7) cis (58 [50]). …”

“…Although few crystallographic examples are reported for Type II(1) rac-trans (9e [62], 21a* [43], 21b* [68], 22a* [69], 22b* [70], 23* [71], 24* [34i]), there are more examples for Type II(1) cis ( 25* [43], 26* [72], 27* [73], 28* [74], 29* [75], 30a* [34i], 30b [76], 31* [77] , 32a* [78], 32b* [79], 32c* [80], 33a [51], 33b-e* [81], 34a* [34j], 34b [34k], 34c[82], 35a,b[83], 36a,b[84], 37* [34e], 38*[85], 39*[86].…”