Reactions of coordinated ligands, part II1). Kinetics of iodination of salicylate in bis(ethylenediamine)(salicylato)cobalt(III) cation

Abstract

SummaryThe rates of iodination of salicylate in the bis-(ethylenediamine)(salicylato)cobalt(lll) complex and free salicylate have been measured in acetate buffer at 40 ° and I = 0.1 M. The reaction is catalysed by acetate and water. The reactivity order for both acetate-and water-catalysed paths is: [HSal]