Reactions of Hypervalent Iodine Reagents in Green Solvents and under Solvent‐Free Conditions

Zhdankin, Viktor V.

doi:10.1002/9781118341155.ch6

Hypervalent Iodine Chemistry 2013

DOI: 10.1002/9781118341155.ch6

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Reactions of Hypervalent Iodine Reagents in Green Solvents and under Solvent‐Free Conditions

Viktor V. Zhdankin

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2022

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Cited by 2 publications

References 67 publications

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A Mechanochemical, Catalyst‐Free Cascade Synthesis of 1,3‐Diols and 1,4‐Iodoalcohols Using Styrenes and Hypervalent Iodine Reagents

et al. 2022

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A mechanochemical and solvent/catalyst-free functionalization of olefins with hypervalent iodine reagents has been developed, enabling the synthesis of 1,3-dioxygenated compounds. Under similar reaction conditions with the addition of molecular iodine, 1,4iodoalcohols can be synthesized. These valuable products are non-trivial to achieve via standard solutionphase methods. Mechanistic study reveals that the hypervalent iodine reagent might dimerize at solid state with the help of mechanical force. The active monomeric form of hypervalent iodine reagent might trigger the 1,3and 1,4-difunctionalization reactions in an intermolecular cascade manner.

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A Mechanochemical, Catalyst‐Free Cascade Synthesis of 1,3‐Diols and 1,4‐Iodoalcohols Using Styrenes and Hypervalent Iodine Reagents

et al. 2022

View full text Add to dashboard Cite

show abstract

A Mechanochemical, Catalyst‐Free Cascade Synthesis of 1,3‐Diols and 1,4‐Iodoalcohols Using Styrenes and Hypervalent Iodine Reagents

et al. 2022

View full text Add to dashboard Cite

show abstract

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Reactions of Hypervalent Iodine Reagents in Green Solvents and under Solvent‐Free Conditions

Cited by 2 publications

References 67 publications

A Mechanochemical, Catalyst‐Free Cascade Synthesis of 1,3‐Diols and 1,4‐Iodoalcohols Using Styrenes and Hypervalent Iodine Reagents

A Mechanochemical, Catalyst‐Free Cascade Synthesis of 1,3‐Diols and 1,4‐Iodoalcohols Using Styrenes and Hypervalent Iodine Reagents

A Mechanochemical, Catalyst‐Free Cascade Synthesis of 1,3‐Diols and 1,4‐Iodoalcohols Using Styrenes and Hypervalent Iodine Reagents

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