Reactions of MoOCl4 with 1-Methylimidazole, 1,4-Diaminobutane, 2-Methylpyridine, 2-Methylpiperidine, Trimethylsilylimidazole and 1-Methylpyrrolidine

Abstract

MoOCl4 reacts with 1-methylimidazole, 4-methylpiperidine and trimethylsilylimidazole (equimolar molar amounts) in solvent CH3CN to provide MoO2Cl4(C3H3N2CH3) [1], MoOCl4(C5H9NHCH3)CH3CN [4] and MoO2Cl2(C3H4N2), [7]. MoOCl4 reacts with twice the moles of 1,4-diaminobutane, 2-methylpyridine, 4-methylpiperidine and 1-methylpyrrolidine in solvent CH3CN to provide: MoOCl4(H2NC4H8NH2)2 [2], MoOCl4(C5H4NCH3), [3], MoOCl4(C5H9NHCH3)2, [5], MoOCl4(C5H9NHCH3)2, [6] and MoO2Cl4(C4H8NCH3)2, [8]. Complexes have been studied by techniques: elemental quantitative analysis, FTIR, 1H NMR, Mass (LC-MS).

Reactions of MoO2Cl2 and MoOCl4 with 2-Mercaptopyridine, 4-Phenylimidazole-2-thiol and 6-Mercaptopurine Monohydrate

“…The author earlier also investigated [31][32][33][38][39] reactions of MoOCl 4 with various diaminoalkanes, amides, imides, alkylpyridines, mercaptopyridine, mercaptopyridine-N-oxide sodium, 2-thiazoline-2thiol, alkylpyrrolidine, alkylpiperidine and aromatic azoles.…”

Reactions of MoOCl4 and MoO2Cl2 with Heterocyclic Thioamides

“…Many complexes of alkylpyr idines, amides, alkylpyrrolidine, alkylpiperidine, aromatic azoles, diaminoalkanes, imides, mercaptopyridine, mercaptopyridine-N-oxide sodium, purine and 2-thiazoline-2-thiol with MoOCl 4 have also been reported [33][34][35][40][41][42] by the author.…”