Dalton Trans.
 2022
DOI: 10.1039/d2dt01344d
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Reactions of permethyltitanocene tucked-in derivatives with carbon dioxide

Jiřı́ Pinkas
1
,
Róbert Gyepes
2
,
Miroslav Polášek
3
et al.

Abstract: Both single tucked-in permethyltitanocene 1 and double tucked-in permethyltitanocene 2 react with excess CO2 by insertion into their Ti–CH2 bond. The former one precipitates instantly a yellow carboxylate-tethered oligomer [3]n...

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